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In Luxembourg it is mandatory to purchase a Eurovignette for goods vehicles of 12 tonnes or more, to circulate on the road network, consisting of six motorways with a length of 152km. The country has joined the Netherlands, Denmark and Sweden in organizing the process and collection of the fee through AGES.
If you are going to travel to Luxembourg, you must bear in mind that the acquisition of the vignette for the toll must be made prior to entering the country. In no case will it be valid retroactively.
You can buy your vignette at this link.